12th Class Chemistry Alcohols, Phenols and Ethers / एल्कोहॉल, फीनॉल तथा ईथर Question Bank 12th CBSE Chemistry Alcohols, Phenols and Ethers

  • question_answer
    How do you account for the fact that unlike phenol, 2,4-dinitrophenol is soluble in aqueous sodium carbonate solution?

    Answer:

                    The presence of two electron withdrawing \[-N{{O}_{2}}\]groups in the ring at the ortho and para positions makes 2,4-dinitrophenol a stronger acid than phenol. It therefore, reacts with aqueous sodium cartonate to form corresponding sodium salt which is soluble. But phenol being a weaker acid does not react with aqueous sodium carbonate. For more details, consult section 12.16.


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