12th Class Chemistry Aldehydes, Ketones and Carboxylic Acids / ऐल्डिहाइड, कीटोन तथा कर्बोक्सिलिक अम्ल Question Bank 12th CBSE Chemistry Aldehydes, Ketones

  • question_answer
    Dipole moments of aldehydes and ketones are higher than those of alcohols. Explain.

    Answer:

                    The \[\pi \]-electrons of the  arc loosely held and hence can be shifted towards O-atom more readily than the more tightly held \[\sigma \]-electrons of the \[C-O\] bond in alcohols. Consequently, the magnitude of the +ve and ?ve charge developed in  bond is higher than those on \[C-O\] bond of alcohols. As a result, the dipole moment of aldehydes and ketones (2.3-2.8 D) is much higher than that of alcohols (1.6 - 1.8 D).


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