12th Class Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank 12th CBSE Chemistry The d-and f-Block Elements

  • question_answer
        The atomic radii of the elements in a transition series do not vary much while they do vary in case of s and p block elements. Explain.

    Answer:

                                      In case of transition elements, the electrons are filled in \[(n-1)\] d-sub-shell and they exert screening effect as a result of which the atomic size is expected to increase. Thus, as we move from left to the right in a transition series, the increase in the magnitude of nuclear charge (leading to decrease in size) is almost balanced by the increase in the shielding effect (leading to increase in size). Because of these two opposing tendencies, there is a very small change in the atomic size (or atomic radii) as we move along the transition series. In s and p-block elements, as we move along a period the electrons are filled in the valence s and p orbitals. These electrons do not exert as much screening effect as are exerted by the electrons present in the d-orbitals. There is a gradual increase in effective nuclear change leading to decrease in atomic size along a particular period.


You need to login to perform this action.
You will be redirected in 3 sec spinner