JEE Main & Advanced Chemistry Hydrocarbons / हाइड्रोकार्बन Question Bank Alkyne

  • question_answer
    A gas decolourises bromine in \[CC{{l}_{4}}\] and forms a precipitate with ammoniacal silver nitrate. The gas is [EAMCET 1998]

    A) \[{{C}_{2}}{{H}_{2}}\]

    B) \[{{C}_{2}}{{H}_{4}}\]

    C) \[{{C}_{2}}{{H}_{6}}\]

    D) \[C{{H}_{4}}\]

    Correct Answer: A

    Solution :

           \[CH\equiv CH+2B{{r}_{2}}\xrightarrow{CC{{l}_{4}}}\underset{\underset{Br\,}{\mathop{|\,\,\,\,}}\,}{\overset{\overset{Br}{\mathop{|\,\,\,\,}}\,}{\mathop{CH}}}\,-\underset{\underset{Br\,}{\mathop{|\,\,\,\,}}\,}{\overset{\overset{Br\,}{\mathop{|\,\,\,\,}}\,}{\mathop{CH}}}\,\] \[CH\equiv CH+N{{H}_{4}}OH+AgN{{O}_{3}}\to \underset{\begin{smallmatrix}  \text{Di-silver}\,\text{acetylide} \\  \,\,\,\,\,\,\,\text{white}\,\text{ppt}\text{.} \end{smallmatrix}}{\mathop{Ag-C\equiv C-Ag}}\,\]


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