JEE Main & Advanced Chemistry The d-and f-Block Elements / d तथा f ब्लॉक के तत्व Question Bank Compounds of Transitional Elements

  • question_answer
    \[{{F}_{2}}\] is the formed by reacting \[{{K}_{2}}Mn{{F}_{6}}\] with [AIIMS 2005]

    A) \[Sb{{F}_{5}}\]

    B) \[Mn{{F}_{3}}\]

    C) \[KSb{{F}_{6}}\]

    D) \[Mn{{F}_{4}}\]

    Correct Answer: A

    Solution :

    \[{{K}_{2}}Mn{{F}_{6}}~+2Sb{{F}_{5}}\to 2KSb{{F}_{6}}+Mn{{F}_{3}}+\frac{1}{2}{{F}_{2}}\] In this reaction, the stronger Lewis acid\[Sb{{F}_{5}}\]displaces the weaker one,\[Mn{{F}_{4}}\]from its salt.\[Mn{{F}_{4}}\]is unstable and readily decomposes to give \[Mn{{F}_{3}}\]and fluorine.


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