JEE Main & Advanced Chemistry The p-block Elements-II / p-ब्लॉक तत्व-II Question Bank Oxygen Family

  • question_answer
    On controlled hydrolysis and condensation, \[{{R}_{3}}SiCl\] yields [Orissa JEE 2005]

    A) \[{{R}_{3}}Si-O-Si{{R}_{3}}\]

    B) (\[\,{{R}_{3}}Si-O-Si{{R}_{3}}\,\])n

    C) \[{{R}_{3}}SiOH\]

    D) \[\overset{R\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,R}{\mathop{\overset{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|}{\mathop{\overset{-Si\,\,-\,O\,\,-Si\,-}{\mathop{\underset{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|\,}{\mathop{\underset{-Si-O-Si-}{\mathop{\underset{O\,\,\,\,\,\,\,\,\,\,\,\,\,\,O}{\mathop{|\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,|}}\,}}\,}}\,}}\,}}\,}}\,\]

    Correct Answer: A

    Solution :

    \[{{R}_{3}}SiCl\] on hydrolysis forms only a dimer. \[{{R}_{3}}SiOH+HOSi{{R}_{3}}\to {{R}_{3}}Si-O-Si{{R}_{3}}\].


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