JEE Main & Advanced Chemistry Haloalkanes and Haloarenes / हैलोएल्केन तथा हैलोएरीन्स Question Bank Properties of Halogen Containing Compounds

  • question_answer
    Among the following, the one which reacts most readily with ethanol is [AIIMS 2004]

    A) p-nitrobenzyl bromide

    B) p-chlorobenzyl bromide

    C) p-methoxybenzyl bromide

    D) p-methylbenzyl bromide

    Correct Answer: C

    Solution :

      Due to the presence of electron rich methoxy group (+I) at p-position the polarity increase on C-X bond by which it becomes more reactive towards nucleophillic attack of ethanol, p-nitro and chloro are electron deficient group decrease the polarity of C-X bond. Hence by them it become difficult to react with ethanol due to less polarity. Methyl group is less electron rich than methoxy group.


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