JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Volumetric Analysis

  • question_answer
    20 ml of a solution of a weak monobasic acid neutralizes 22.18 ml of a solution of NaOH and 20 ml of N/10 HCl neutralizes 21.5 ml of the same NaOH solution. The normality for the acid is nearly [MP PET 2002]

    A) 10 N

    B) 1 N

    C) 0.10 N

    D) 100 N

    Correct Answer: C

    Solution :

    \[{{N}_{1}}{{V}_{1}}={{N}_{2}}{{V}_{2}}\] \[{{N}_{1}}\times 20={{N}_{2}}\times 22.18\] \[{{N}_{1}}=\frac{{{N}_{2}}\times 22.18}{20}\]  ???(i) \[NaOH\]solution = \[HCl\]solution \[{{N}_{2}}\times 21.5=\frac{1}{10}\times 20\] \[{{N}_{2}}=\frac{20}{10\times 21.5}\]     ??.(ii) by eq. (i) and (ii) \[{{N}_{1}}=\frac{20\times 22.18}{20\times 10\times 21.5}=\frac{22.18}{215}=0.1N\]


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