JEE Main & Advanced Chemistry Analytical Chemistry Question Bank Wet Test for Acid Radical

  • question_answer
    Chromyl chloride vapours are dissolved in \[NaOH\] and acetic acid and lead acetate solution is added, then

    A) The solution will remain colourless

    B) The solution will become dark green

    C) A yellow solution will be obtained

    D) A yellow precipitate will be obtained

    Correct Answer: D

    Solution :

    \[Cr{{O}_{2}}C{{l}_{2}}\ \xrightarrow{NaOH}\ N{{a}_{2}}Cr{{O}_{4}}\ \underset{C{{H}_{3}}COOPb}{\mathop{\xrightarrow{C{{H}_{3}}COOH}}}\,\] \[\left[ {{(C{{H}_{3}}COO)}_{2}}Pb \right]\ \xrightarrow{Cr{{O}_{2}}C{{l}_{2}}}\ \to \ \underset{\text{yellow ppt}\text{.}}{\mathop{PbCr{{O}_{4}}}}\,\]


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