BCECE Engineering BCECE Engineering Solved Paper-2001

  • question_answer
    The solubility of \[A{{g}_{2}}S\]is \[[{{K}_{sp}}=256\times {{10}^{-6}}]:\]

    A) \[4\times {{10}^{-2}}\]        

    B)        \[4\times {{10}^{-3}}\]

    C) \[0.4\times {{10}^{-2}}\]    

    D)        \[0.4\times {{10}^{-3}}\]

    Correct Answer: A

    Solution :

    Key Idea: Let solubility of \[A{{g}_{2}}S=x\,g/L\] \[\underset{\text{Concentration}}{\mathop{A{{g}_{2}}S}}\,\xrightarrow{{}}\underset{2x}{\mathop{A{{g}^{+}}}}\,+{{\underset{x}{\mathop{S}}\,}^{2-}}\] \[{{K}_{sp}}={{[A{{g}^{+}}]}^{2}}[{{S}^{2-}}]\] \[={{(2x)}^{2}}(x)\] \[=4{{x}^{3}}\] Given,  \[{{K}_{sp}}=256\times {{10}^{-6}}\] \[\therefore \]      \[256\times {{10}^{-6}}=4{{x}^{3}}\] or            \[x=\sqrt[3]{\frac{25\times {{10}^{-6}}}{4}}\]                 \[=4\times {{10}^{-2}}\]


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