BCECE Engineering BCECE Engineering Solved Paper-2010

  • question_answer
    A saturated solution of \[\text{A}{{\text{g}}_{\text{2}}}\text{S}{{\text{O}}_{\text{4}}}\]is \[\text{2}\text{.5}\times {{10}^{-2}}\,M.\] The value of its solubility product is

    A)  \[62.5\times {{10}^{-6}}\]           

    B)         \[62.5\times {{10}^{-4}}\]           

    C)         \[15.625\times {{10}^{-6}}\]      

    D)  \[3.125\times {{10}^{-6}}\]

    Correct Answer: A

    Solution :

    Given, solubility of \[A{{g}_{2}}S{{O}_{4}}=2.5\times {{10}^{-2}}M\] Let the solution of \[A{{g}_{2}}S{{O}_{4}}=x\,mol/L\,\] \[\underset{x}{\mathop{A{{g}_{2}}S{{O}_{4}}}}\,\xrightarrow{{}}\underset{2x}{\mathop{2A{{g}^{+}}}}\,+\underset{x}{\mathop{SO_{4}^{2-}}}\,\] \[{{K}_{sp}}=[A{{g}^{+}}][SO_{4}^{2-}]\] \[={{(2x)}^{2}}(x)\] \[=4{{x}^{3}}\] \[=4\times {{(2.5\,\times \,{{10}^{-2}})}^{3}}\] \[=62.5\times {{10}^{-6}}\]


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