BCECE Engineering BCECE Engineering Solved Paper-2013

  • question_answer
    \[{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}\]oxidizes \[\text{Mn}{{\text{O}}_{\text{2}}}\]is \[\text{MnO}_{4}^{-}\]in basic  medium, \[{{\text{H}}_{\text{2}}}{{\text{O}}_{\text{2}}}\]and \[\text{Mn}{{\text{O}}_{\text{2}}}\]react in the molar ratio of

    A) 1 : 1     

    B)                        2 : 1       

    C)        2 : 3       

    D)        3 : 2

    Correct Answer: D

    Solution :

    (Oxidation number two O atoms taken) On balancing of oxidation number                 \[3{{H}_{2}}{{O}_{2}}+2Mn{{O}_{2}}\xrightarrow{{}}2MnO_{4}^{-}+6{{H}_{2}}O\] Thus,   \[{{H}_{2}}{{O}_{2}}:Mn{{O}_{2}}=3:2\]


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