BCECE Medical BCECE Medical Solved Papers-2008

  • question_answer
    The following data are for the decomposition of ammonium nitrite in aqueous solution.
    Vol. of \[{{N}_{2}}\] in cc Time (min)
    6.25 10
    9.00 15
    11.40 20
    13.65 25
    35.65 Infinity
    The order of reaction is

    A)  zero           

    B)  one

    C)  two   

    D)  three

    Correct Answer: B

    Solution :

    For first order reaction, \[k=\frac{2.303}{t}\log \frac{a}{a-x}\] \[a\propto {{V}_{\infty }}(=35.-05)\] and \[x\propto {{V}_{t}}\]. Constant values of k calculated for different times, shows first order reaction.


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