BCECE Medical BCECE Medical Solved Papers-2013

  • question_answer
    mL of an aqueous solution of KC1 was found to require 20 mL of 1 M \[AgN{{O}_{3}}\] solution when titrated using a \[{{K}_{2}}Cr{{O}_{4}}\] as indicator. Depression in freezing point of \[KCl\] solution with 100% ionisation will be [\[{{K}_{F}}={{2.0}^{o}}\,mo{{l}^{-1}}kg\], molarity = molality]

    A)  \[{{3.2}^{o}}\]

    B)  \[{{1.6}^{o}}\]

    C)  \[{{0.8}^{o}}\]             

    D)  \[{{5.0}^{o}}\]

    Correct Answer: A

    Solution :

    \[\frac{KCl}{{{M}_{1}}{{V}_{1}}}=\frac{AsN{{O}_{3}}}{{{M}_{2}}{{V}_{2}}}\]                 \[{{M}_{1}}=\frac{1\times 20}{25}\]                 \[=0.8\,M\]                 \[i=(1+x)\]                 \[=1+1=2\] \[\therefore \] \[\Delta {{T}_{f}}=\] molality \[\times \,{{K}_{f}}\times i\]                 \[=0.8\times 2\times 2\] \[={{3.2}^{o}}\]


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