BCECE Medical BCECE Medical Solved Papers-2015

  • question_answer
    Given that, \[E_{F{{e}^{2+}}/Fe}^{o}=-0.44\,\,V\], \[E_{F{{e}^{2+}}/F{{e}^{3+}}}^{o}=-0.77\,\,V\]. If \[F{{e}^{2+}},F{{e}^{3+}}\] and Fe solid are kept together, then

    A)  \[F{{e}^{3+}}\] decreases

    B)  \[F{{e}^{3+}}\] increases

    C)  \[F{{e}^{2+}}\] decreases

    D)  \[F{{e}^{2+}},F{{e}^{3+}}\] remain unchanged

    Correct Answer: A

    Solution :

    Cell reaction, \[2\,F{{e}^{3+}}+Fe\xrightarrow{{}}3F{{e}^{2+}}\]                 \[E_{cell}^{o}=0.77-(-0.44)=1.21\,V\] \[\Rightarrow \] \[F{{e}^{3+}}\] and Fe will reduce.


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