A) \[N{{O}_{2}}\]
B) \[{{H}_{2}}\overset{\,\,\bullet \,\,\bullet }{\mathop{N}}\,C{{H}_{2}}C{{H}_{2}}\overset{\,\,\bullet \,\,\bullet }{\mathop{N}}\,{{H}_{2}}\]
C) \[{{H}_{2}}O\]
D) \[_{\bullet }^{\bullet }N{{H}_{3}}\]
Correct Answer: A
Solution :
\[NO_{2}^{-}\] can participate in linkage isomerism because it may be bonded to metal through nitrogen or through oxygen. \[\underset{\begin{smallmatrix} Pentaamminenitro \\ cobalt\text{ (}III\text{) }chloride \end{smallmatrix}}{\mathop{[\,{{(N{{H}_{3}})}_{5}}CoN{{O}_{2}}]C{{l}_{2}}}}\,\] and \[\underset{\begin{smallmatrix} Pentaamminenitro \\ cobalt\text{ (}III\text{) }chloride \end{smallmatrix}}{\mathop{[\,{{(N{{H}_{3}})}_{5}}CoONO]C{{l}_{2}}}}\,\]
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