CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2010

  • question_answer
    Chloroacetic acid is a stronger acid than acetic acid. This can be explained using

    A) -M effect            

    B) -I effect

    C) + M effect          

    D) +I effect

    Correct Answer: B

    Solution :

    \[-Cl\] is an electron withdrawing (ie, \[-I\] showing) group. It withdraws electrons when attached to the carboxylic acid and decreases the electron density on the oxygen atom. This will facilitate the release of H+ by making\[O-H\] bond more polar and thus \[-Cl\]increases the acidity of acetic acid when attached at, a position because of \[-I\] effect.


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