CET Karnataka Engineering CET - Karnataka Engineering Solved Paper-2011

  • question_answer
    \[50\text{ }c{{m}^{3}}\] of \[0.2\text{ }N\text{ }HCl\] is titrated against\[0.1\text{ }N\text{ }NaOH\] solution. The titration was discontinued after adding \[50\text{ }c{{m}^{3}}\] of \[NaOH\]. The remaining titration is completed by adding \[0.5\text{ }N\text{ }KOH\]. The volume of \[KOH\]required for completing the titration is

    A)  \[12\,\,c{{m}^{3}}\]                                      

    B)  \[10\,\,c{{m}^{3}}\]

    C)  \[21.0\,\,c{{m}^{3}}\]                   

    D)  \[16.2\,\,c{{m}^{3}}\]

    Correct Answer: B

    Solution :

    No. of equivalent of \[HCl\] remaining after adding \[50\,c{{m}^{3}}\]of \[0.1\,N\,NaOH=\frac{0.2\times 50-0.1\times 50}{100}\]                                                 \[=\frac{0.5}{100}\] \[\therefore \] Volume of \[0.5\text{ }N\text{ }KOH\] required \[=\frac{0.5}{100}eq\]                 \[\equiv \frac{V\times 0.5}{1000}\]                 \[V=\frac{0.5}{100}\times \frac{1000}{0.5}\]                 \[=10\,\,c{{m}^{3}}\]


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