Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2004

  • question_answer
    Molal depression constant for water is\[{{1.86}^{o}}C\] The freezing point of a \[0.05\]molal solution of a non-electrolyte in water, is

    A)  \[-{{1.86}^{o}}C\]

    B)  \[-{{0.93}^{o}}C\]

    C)  \[-{{0.093}^{o}}C~\]    

    D)  \[{{0.93}^{o}}C\]

    Correct Answer: C

    Solution :

    Molal depression constant \[{{k}_{f}}={{1.86}^{o}}C\] Molality \[=0.05\] \[\Rightarrow \]               \[\Delta {{T}_{f}}={{k}_{f}}\times molality\]                 \[\Delta {{T}_{f}}=1.86\times 0.05\]                 \[\Delta {{T}_{f}}={{0.093}^{o}}C\]                 \[\Delta {{T}_{f}}={{T}_{1}}-{{T}_{2}}\] where, \[{{T}_{1}}\] = freezing point of solvent \[{{T}_{2}}\]= freezing point of solution \[{{T}_{1}}={{0}^{o}}C\] \[0.093=0-{{T}_{2}}\] \[{{T}_{2}}=-0.093\]


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