Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2006

  • question_answer
    Bond order of \[{{N}_{2}}\] molecule is

    A)  3                                            

    B)  2

    C)  1                                            

    D)  0

    Correct Answer: A

    Solution :

    The molecular configuration of \[{{N}_{2}}\] is \[\sigma 1{{s}^{2}},\overset{*}{\mathop{\sigma }}\,1{{s}^{2}}\sigma 2{{s}^{2}}\overset{*}{\mathop{\sigma }}\,2{{s}^{2}}\left\{ \begin{matrix}    \pi 2{{p}_{y}}^{2}  \\    \pi 2{{p}_{x}}^{2}  \\ \end{matrix}\sigma 2{{p}_{z}}^{2} \right.\]                                                 \[\left\{ \begin{matrix}    \overset{*}{\mathop{\pi }}\,2{{p}_{y}}  \\    \overset{*}{\mathop{\pi }}\,2{{p}_{x}}  \\ \end{matrix}\overset{*}{\mathop{\sigma }}\,2{{p}_{z}} \right.\] number of bonding electrons                 \[Bond\text{ }order=\frac{-\text{ }number\text{ }of\text{ }antibonding\text{ }electrons}{2}\] \[=\frac{10-4}{2}\] \[\therefore \] Bond order = 3


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