Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2007

  • question_answer
    44.          \[4.5g\] of aluminium (at. mass 27 u) is deposited at cathode from \[A{{l}^{3+}}\] solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from \[{{H}^{+}}\]ions in solution by the same quantity of electric charge will be

    A)  \[44.8\text{ }L\]              

    B)  \[11.2L\]

    C)  \[22.4\text{ }L\]              

    D)  \[5.6\text{ }L\]

    Correct Answer: D

    Solution :

    After passing same amount of electricity equal gram equivalent of substances deposited or dissolved. So, gram equivalent of aluminium = gram equivalent of hydrogen.                 \[\therefore \] \[\frac{weight\text{ }of\text{ }aluminium}{\begin{align}   & weight\text{ }of\text{ }aluminium \\  & of\,\,\text{aluminium} \\ \end{align}}=\frac{volume\,\,of\,{{H}_{2}}\,at\,STP}{11.2L}\]                      \[\Rightarrow \]               \[\frac{4.5}{9}=\frac{volume\,of\,{{H}_{2}}\,at\,STP}{11.2}\]                 \[\therefore \]    Volume of  \[{{H}_{2}}\]  at STP \[=5.6\text{ }L\]


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