Chhattisgarh PMT Chhattisgarh PMT Solved Paper-2007

  • question_answer
    The strongest oxidising agent amongst \[{{F}_{2}},\] \[C{{l}_{2}};\]\[B{{r}_{2}}\] and \[{{I}_{2}}\] is

    A)  \[{{F}_{2}}\]                     

    B)  \[{{I}_{2}}\]

    C)  \[C{{l}_{2}}\]                    

    D)  \[B{{r}_{2}}\]

    Correct Answer: A

    Solution :

    Since all the halogens have strong tendency to accept electrons, they act as strong oxidising agent. \[{{F}_{2}}+2{{e}^{-}}\xrightarrow{{}}2{{F}^{-}};\,\,\,\,\,\,\,\,\,\,\,\,{{E}^{o}}=+2.87V\] \[C{{l}_{2}}+2{{e}^{-}}\xrightarrow{{}}2C{{l}^{-}};\,\,\,\,\,\,\,\,\,\,\,\,{{E}^{o}}=+1.36V\] \[B{{r}_{2}}+2{{e}^{-}}\xrightarrow{{}}2B{{r}^{-}};\,\,\,\,\,\,\,\,\,\,\,\,{{E}^{o}}=+1.09V\] \[{{I}_{2}}+2{{e}^{-}}\xrightarrow{{}}2{{I}^{-}};\,\,\,\,\,\,\,\,\,\,\,\,{{E}^{o}}=+0.54V\] The electrode potential of F; is the maximum while that of \[{{I}_{2}}\] is the minimum. So, \[{{F}_{2}}\] is the strongest oxidising agent while \[{{I}_{2}}\] is the weakest oxidising agent.


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