CMC Medical CMC-Medical Ludhiana Solved Paper-2014

  • question_answer
    The final product in the following sequence of reaction is\[CH\equiv CH\xrightarrow[{}]{NaN{{H}_{2}}}A\xrightarrow[{}]{C{{H}_{3}}Br}B\]

    A)  \[C{{H}_{2}}=CH-CH=C{{H}_{2}}\]

    B)  \[HC\equiv C-C{{H}_{3}}\]

    C)  \[C{{H}_{2}}=CH-C{{H}_{3}}\]

    D)  \[C{{H}_{3}}-C{{H}_{2}}-C{{H}_{3}}\]

    Correct Answer: B

    Solution :

                    \[CH\equiv CH\xrightarrow{NaN{{H}_{2}}}\underset{A}{\mathop{CH\equiv {{C}^{-}}N{{a}^{+}}}}\,\]\[\xrightarrow[-NaBr]{C{{H}_{3}}Br}CH\equiv \underset{B}{\mathop{C}}\,-C{{H}_{3}}\]


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