CMC Medical CMC-Medical VELLORE Solved Paper-2014

  • question_answer
    The half-life of two samples are 0.1 and 0.8 s. Their respective concentration are 400 and 50 respectively. The order of the reaction is

    A)  0                                            

    B)  2

    C)  1                                            

    D)  4

    Correct Answer: B

    Solution :

              We know that, \[\frac{{{({{t}_{1/2}})}_{1}}}{{{({{t}_{1/2}})}_{2}}}={{\left[ \frac{{{a}_{2}}}{{{a}_{1}}} \right]}^{n-1}}\] where, n = order of the reaction Given,     \[({{t}_{1/2}})=0.1\,s,\]\[\,{{a}_{1}}=400\]           \[{{({{t}_{1/2}})}_{2}}=0.8\,s,\]\[\,{{a}_{2}}=50\] On substituting the values, \[\frac{0.1}{0.8}={{\left[ \frac{50}{400} \right]}^{n-1}}\] On taking log both sides \[\log \frac{0.1}{0.8}=(n-1)\log \frac{50}{400}\] \[\log \frac{1}{8}=(n-1)\log \frac{1}{8}\] \[0.90=(n-1)\,0.90\] \[n-1=1,\]\[n=2\]


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