Haryana PMT Haryana PMT Solved Paper-2009

  • question_answer
    Which will exhibit geometrical isomerism?

    A)  3-phenyl-l-butene

    B)  1-phenyl-2-butene

    C)  2-phenyl-l-butene

    D)  1, 1-diphenyl-l-propene

    Correct Answer: B

    Solution :

                    The compound which has at least one double bond and the groups attached with double bonded carbon atoms are different, exhibits geometrical isomerism.             \[C{{H}_{3}}CH=CHC{{H}_{2}}{{C}_{6}}{{H}_{5}}\]exhibits geometrical isomerism. \[\underset{\begin{smallmatrix}  1-phenyl-2-butene \\  cis\,form \end{smallmatrix}}{\mathop{\begin{matrix}    {{H}_{3}}C & {} & C{{H}_{2}}{{C}_{6}}{{H}_{5}}  \\    {} & C=C & {}  \\    H & {} & H  \\ \end{matrix}}}\,\]                                 \[\underset{trans\,form}{\mathop{\begin{matrix}    {{H}_{3}}C & {} & H  \\    {} & C=C & {}  \\    H & {} & C{{H}_{2}}{{C}_{6}}{{H}_{5}}  \\ \end{matrix}}}\,\]


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