J & K CET Engineering J and K - CET Engineering Solved Paper-2003

  • question_answer
    Aufbau principle does not Jgrve the correct arrangement of filling Up T of atomic orbitals in

    A)  Cu and Zn    

    B)  Co and Zn

    C)  Mn and Cr    

    D)  Cu and Cr

    Correct Answer: D

    Solution :

     Aufbau principle does not give the correct arrangement of filling up of atomic orbitals in copper and chromium because half-filled and completely filled electronic configuration of Cr and Cu have lower energy and therefore, more stable. \[Cr\,(Z=24):\,\,1{{s}^{2}},2{{s}^{2}}2{{p}^{6}},3{{s}^{2}}3{{p}^{6}}3{{d}^{5}},4{{s}^{1}}\] \[Cu(Z=29):1{{s}^{2}},2{{s}^{2}}2{{p}^{6}},3{{s}^{2}}3{{p}^{6}}3{{d}^{10}},4{{s}^{1}}\]


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