A) \[[Co{{(en)}_{3}}]C{{l}_{3}}\]
B) \[[Co{{(en)}_{3}}]C{{l}_{3}}\]
C) \[[Co{{(en)}_{2}}N{{O}_{2}}Cl]Br\]
D) \[[Co{{(N{{H}_{3}})}_{5}}Cl]B{{r}_{2}}\]
Correct Answer: C
Solution :
\[[Co{{(en)}_{2}}N{{O}_{2}}Cl]\,Br\]exhibits linkage isomerism because the \[\text{N}{{\text{O}}_{\text{2}}}\]group can exist as nitrito \[(-ONO)\] and nitro \[(-\text{N}{{\text{O}}_{\text{2}}})\] group. The linkage isomers of\[[Co{{(en)}_{2}}N{{O}_{2}}Cl]Br\]areas: \[[Co{{(en)}_{2}}N{{O}_{2}}Cl]Br\]and \[[Co{{(en)}_{2}}ONOCl]Br\]
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