J & K CET Engineering J and K - CET Engineering Solved Paper-2012

  • question_answer
    A nucleophilic substitution reaction proceeds through \[{{\text{S}}_{\text{N}}}\text{1}\]mechanism. So, the reaction is

    A)  unimolecular

    B)  bimolecular

    C)  trimolecular

    D)  rate depends on concentration of incoming nucleophile

    Correct Answer: A

    Solution :

     A nucleophilic substitution reaction proceeds through\[{{\text{S}}_{\text{N}}}\text{1}\]mechanism, so the reaction is unimolecular. \[C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,\xrightarrow{\text{Slow}}C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{|}{\mathop{{{C}^{+}}}}}\,}}}\,+B{{r}^{-}}\] \[C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{|}{\mathop{{{C}^{+}}}}}\,}}}\,+O{{H}^{-}}\xrightarrow{\text{Fast}}C{{H}_{3}}-\underset{C{{H}_{3}}}{\overset{C{{H}_{3}}}{\mathop{\underset{|}{\overset{|}{\mathop{C}}}\,}}}\,-OH\] \[\text{Rate}\propto [{{3}^{o}}\,\text{alkyl}\,\text{halide}\,]\]


You need to login to perform this action.
You will be redirected in 3 sec spinner