J & K CET Engineering J and K - CET Engineering Solved Paper-2015

  • question_answer
    If \[{{E}^{o}}_{{{M}^{+}}/M}=-1.2V,{{E}^{o}}_{{{x}_{2}}/{{x}^{-}}}=-1.1\,V\]and \[{{E}^{o}}_{{{o}_{2}}/{{H}_{2}}O}=1.23\,V,\]then on electrolysis of aqueous solution of salt MX, the products obtained are

    A) \[M,{{X}_{2}}\]

    B) \[{{H}_{2}},{{X}_{2}}\]

    C)  \[{{H}_{2}},{{O}_{2}}\]

    D)  \[M,{{O}_{2}}\]

    Correct Answer: B

    Solution :

     Given, \[{{E}^{o}}_{{{M}^{+}}/M}=-1.2\,V\] \[{{E}^{o}}_{{{x}_{2}}/{{x}^{-}}}=-1.1\,V\] \[{{E}^{o}}_{{{O}_{2}}/{{H}_{2}}O}=1.23\,V\] On electrolysis of aqueous solution of salt MX.  The products obtained depends on the given \[{{\text{E}}^{\text{o}}}\]values i.e. cathodic reaction will be one with higher \[{{\text{E}}^{\text{o}}}_{\text{red}}\]value. Anodic reaction will be one with higher \[{{\text{E}}^{\text{o}}}_{oxi}\]value or lower \[{{\text{E}}^{\text{o}}}_{red}\]value. Hence, the products are \[{{H}_{2}}\]and \[{{X}_{2}}.\]


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