JAMIA MILLIA ISLAMIA Jamia Millia Islamia Solved Paper-2012

  • question_answer
    The example of Friedel-Crafts reaction is

    A)  \[{{C}_{6}}{{H}_{6}}+{{C}_{2}}{{H}_{5}}Cl\xrightarrow[{}]{AlC{{l}_{3}}}{{C}_{6}}{{H}_{5}}{{C}_{2}}{{H}_{5}}\]\[+HCl\]

    B)  \[{{C}_{2}}{{H}_{5}}OH+HCl\xrightarrow[{}]{ZnC{{l}_{2}}}{{C}_{2}}{{H}_{5}}Cl+{{H}_{2}}O\]

    C)  \[{{C}_{6}}{{H}_{5}}Cl+C{{H}_{3}}COCl\xrightarrow[{}]{AlC{{l}_{3}}}{{C}_{6}}{{H}_{5}}COC{{H}_{3}}\]\[+C{{l}_{2}}\]

    D)  \[{{C}_{6}}{{H}_{5}}Br+Mg\xrightarrow[{}]{Ether}{{C}_{2}}{{H}_{5}}MgBr\]

    Correct Answer: A

    Solution :

                    Alkyl substituted benzenes are prepared by the reaction between benzene and alkyl halide in the presence of a Lewis acid\[(AlC{{l}_{3}},\text{ }B{{F}_{3}},\text{ }FeC{{l}_{3}},\]etc.) This reaction is known as Friedel-Crafts reaction.


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