JCECE Engineering JCECE Engineering Solved Paper-2004

  • question_answer
    Benzaldehyde, in presence of \[dil.\,\,NaOH,\]changes into benzyl alcohol and sodium benzoate. This reaction is an example of:

    A)  rearrangement

    B)  oxidation

    C)   disproportionation

    D)   hone of the above

    Correct Answer: C

    Solution :

    Key Idea: Define all terms to find correct answer. [a] Rearrangement reaction: The atoms within molecule change their position during rearrangement reaction. [b] Oxidation: Oxygen adds during oxidation reaction. [c] Disproportionation: During this reaction half of the molecules of some substance are oxidised and other half are reduced. \[\underset{benzaldehyde}{\mathop{{{C}_{6}}{{H}_{5}}CHO}}\,+NaOH\xrightarrow{{}}\underset{sodium\,\,benzoate}{\mathop{{{C}_{6}}{{H}_{5}}COONa}}\,\] \[\underset{benzyl\,\,alcohol}{\mathop{+{{C}_{6}}{{H}_{5}}C{{H}_{2}}OH}}\,\] \[\because \]Half of \[{{C}_{6}}{{H}_{5}}CHO\] molecules are oxidised to acid and other half of molecules are reduced to alcohol. \[\therefore \]It is disproportionation reaction.


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