JCECE Engineering JCECE Engineering Solved Paper-2008

  • question_answer
    Excess of \[KI\] reacts with \[CuS{{O}_{4}}\] solution and then \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\] solution is added to it. Which of the statements is incorrect for this reaction?

    A) \[C{{u}_{2}}{{I}_{2}}\] is formed

    B)  \[Cu{{I}_{2}}\]is formed

    C) \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\]is oxidised

    D)   Evolved\[{{I}_{2}}\]is reduced

    Correct Answer: B

    Solution :

    \[CuS{{O}_{4}}+2KI\xrightarrow{{}}\underset{unstable}{\mathop{Cu{{I}_{2}}}}\,+{{K}_{2}}S{{O}_{4}}\] \[2Cu{{I}_{2}}\xrightarrow[{}]{{}}C{{u}_{2}}{{I}_{2}}+{{I}_{2}}\] Thus, \[Cu{{I}_{2}}\] is not formed.


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