JCECE Engineering JCECE Engineering Solved Paper-2010

  • question_answer
    The most reactive compound towards formation of cyanohydrin on treatment with HCN followed by acidification is

    A)  benzaldehyde

    B)  \[p-\]nitrobenzaldehyde

    C)  phenylacetaldehyde

    D)   \[p-\]hydroxybenzaldehyde

    Correct Answer: B

    Solution :

    Addition of \[HCN\] to a carbonyl compound is a nucleophilic addition reaction. \[-N{{O}_{2}}\] group being electron withdrawing increases the polarity (or electron deficiency) of carbonyl carbon and thus, makes the \[>C=O\] group of behzaldehyde more reactive towards\[HCN\].


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