JCECE Engineering JCECE Engineering Solved Paper-2011

  • question_answer
    Which of the following compounds corresponds to van't Hoff factor \[(i)\] to be equal to \[2\] for dilute solution?

    A) \[{{K}_{2}}S{{O}_{4}}\]                 

    B) \[NaHS{{O}_{4}}\]

    C) \[Sugar\]                            

    D) \[MgS{{O}_{4}}\]

    Correct Answer: D

    Solution :

    \[i=2\]means two ions are present in the solution.                 \[{{K}_{2}}S{{O}_{4}}\xrightarrow{{}}\underbrace{2{{K}^{+}}+SO_{4}^{2-}}_{3\,\,ions}\]                 \[NaHS{{O}_{4}}\xrightarrow{{}}\underbrace{N{{a}^{+}}+{{H}^{+}}+SO_{4}^{2-}}_{3\,\,ions}\]                 \[Sugar\xrightarrow{{}}No\,\,ions\]                 \[MgS{{O}_{4}}\xrightarrow{{}}\underbrace{M{{g}^{2+}}+SO_{4}^{2-}}_{2\,\,ions}\] Thus, van't Hoff factor is 2 for dilute solution of\[MgS{{O}_{4}}\].


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