JCECE Medical JCECE Medical Solved Paper-2014

  • question_answer
    Standard enthalpy and standard entropy change for the oxidation of \[\text{N}{{\text{H}}_{\text{3}}}\]at 298 K are \[-382.64\,\text{kJ}\,\text{mo}{{\text{l}}^{-1}}\]and\[-145.6\,\text{J}\,\text{mo}{{\text{l}}^{-1}}\] respectively. Standard Gibbs energy change for the same reaction at 298 K is

    A) \[+\,339.3\text{ kJ}\,\text{mo}{{\text{l}}^{-1}}\]    

    B) \[~-\text{ }439.3\text{ kJ}\,\text{mo}{{\text{l}}^{-1}}\]

    C) \[-\text{ }339.3\text{ kJ mo}{{\text{l}}^{-1}}\]    

    D) \[~-\text{ }393.3\text{ kJ mo}{{\text{l}}^{-1}}\]

    Correct Answer: D

    Solution :

     \[\Delta {{G}^{o}}=\Delta {{H}^{o}}-T\Delta {{S}^{o}}\] \[=-382.64-298\times (-145.6\times {{10}^{-3}})\] \[=-339.3\,kJ\,mo{{l}^{-1}}\]


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