Manipal Medical Manipal Medical Solved Paper-2005

  • question_answer
    \[{{C}_{6}}{{H}_{5}}-CH=CHCHO\xrightarrow[{}]{X}\] \[{{C}_{6}}{{H}_{5}}CH=\text{ }CHC{{H}_{2}}OH\] In the above sequence X can be:

    A)  \[{{H}_{2}}/Ni\]        

    B)  \[NaB{{H}_{4}}\]

    C)  \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}/{{H}^{+}}\]  

    D)  both [a] and [b]

    Correct Answer: B

    Solution :

     \[NaB{{H}_{4}}\]and\[LiAl{{H}_{4}}\]attacks only carbonyl group and reduce it into alcohol group. They do not attack on double bond. \[\underset{Cinnamic\text{ }aldehyde}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CHCHO}}\,\xrightarrow[{}]{NaB{{H}_{4}}}\] \[\underset{Cinnamic\text{ }alcohol}{\mathop{{{C}_{6}}{{H}_{5}}-CH=CH.C{{H}_{2}}OH}}\,\]


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