Manipal Medical Manipal Medical Solved Paper-2007

  • question_answer
    Chloropicrin is obtained by the reaction of

    A)  steam on carbon tetrachloride

    B)  nitric acid on chlorobenzene

    C)  chlorineon picric acid

    D)  nitric acid on chloroform

    Correct Answer: D

    Solution :

     Chloroform on reaction with nitric acid give chloropicrin (nitro chloroform) according to following reaction \[CHC{{l}_{3}}+HN{{O}_{3}}\xrightarrow[{}]{{}}\underset{\begin{smallmatrix}  Nitro\text{ }chloroform \\  \,\,\,\,(chloropicrin) \end{smallmatrix}}{\mathop{C(N{{O}_{2}})C{{l}_{3}}}}\,+{{H}_{2}}O\]


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