Manipal Medical Manipal Medical Solved Paper-2009

  • question_answer
    The standard emf of a cell involving one electron charge is found to be 0.591 V at\[25{}^\circ C\] The equilibrium constant of the reaction is \[(1F=96500\text{ }C\text{ mo}{{\text{l}}^{-1}},\text{ }R=8.314\text{ }J\text{ }{{K}^{-1}}mo{{l}^{-1}})\]

    A)  \[1.0\times {{10}^{1}}\]       

    B)  \[1.0\times {{10}^{30}}\]

    C)  \[1.0\times {{10}^{10}}\]       

    D)  \[1.0\times {{10}^{5}}\]

    Correct Answer: C

    Solution :

     At 298 K \[E{}^\circ =\frac{0.0591}{n}\log {{K}_{c}}\] \[0.591=\frac{0.0591}{1}\log {{K}_{c}}\] \[\log {{K}_{c}}=\frac{0.5910}{0.0591}\] \[\log {{K}_{c}}=10\] \[{{K}_{c}}={{10}^{10}}\]


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