Manipal Medical Manipal Medical Solved Paper-2010

  • question_answer
    \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and\[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\]exhibit which type of isomerism?

    A)  Geometrical    

    B)  Optical

    C)  Linkage        

    D)  lonisation

    Correct Answer: D

    Solution :

     \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\]and\[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\]give different ions when subjected to ionisation. Thus, these are ionisation isomers and they exhibit ionisation isomerism. \[[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]N{{O}_{2}}\to {{[Co{{(N{{H}_{3}})}_{4}}C{{l}_{2}}]}^{+}}+NO_{2}^{-}\] \[[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]Cl\to {{[Co{{(N{{H}_{3}})}_{4}}ClN{{O}_{2}}]}^{+}}+C{{l}^{-}}\]


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