RAJASTHAN ­ PET Rajasthan PET Solved Paper-2001

  • question_answer
    Correct order of bond length is

    A)  \[HC\equiv CH>{{H}_{2}}C=C{{H}_{2}}>{{H}_{3}}C-C{{H}_{3}}\]

    B)  \[{{H}_{2}}C=C{{H}_{2}}>HC\equiv CH>{{H}_{3}}C-C{{H}_{3}}\]

    C)  \[C{{H}_{3}}-C{{H}_{3}}>C{{H}_{2}}=C{{H}_{2}}>HC\equiv CH\]

    D)  \[C{{H}_{3}}-C{{H}_{3}}>HC\equiv CH>{{H}_{2}}C=C{{H}_{2}}\]

    Correct Answer: C

    Solution :

     Bond length decreases on increasing the bond order. Hence, the order of bond length is \[C-C(1.54\overset{o}{\mathop{\text{A}}}\,)>C=C(1.34\overset{o}{\mathop{\text{A}}}\,)>C\equiv \] \[C(1.20\overset{o}{\mathop{\text{A}}}\,)\]


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