RAJASTHAN ­ PET Rajasthan PET Solved Paper-2001

  • question_answer
    Keto-enol isomerism shows

    A)  \[{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}\]

    B)  \[{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-{{C}_{6}}{{H}_{5}}\]

    C)  \[{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-C{{(C{{H}_{3}})}_{3}}\]

    D)  \[{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-H\]

    Correct Answer: A

    Solution :

     \[\alpha -H\]containing carbonyl group shows keto-enol isomerism. \[\underset{keto}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  O \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}}}\,\underset{enol}{\mathop{{{C}_{6}}{{H}_{5}}-\underset{\begin{smallmatrix}  || \\  OH \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{2}}}}\,\]


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