A) \[C{{H}_{3}}N{{H}_{2}}\]
B) \[{{(C{{H}_{3}})}_{2}}NH\]
C) \[{{(C{{H}_{3}})}_{3}}N\]
D) \[{{(C{{H}_{3}})}_{4}}{{N}^{\oplus }}\]
Correct Answer: A
Solution :
Primary amine reacts with chloroform and alcoholic solution of KOH to form bad smell compound of isocyanide. This reaction is called carbylamine reaction. \[\underset{methyl\text{ }amine}{\mathop{C{{H}_{3}}N{{H}_{2}}}}\,+CHC{{l}_{3}}+3KOH\xrightarrow[{}]{{}}\] \[\underset{methyl\text{ }isocyanide}{\mathop{C{{H}_{3}}NC}}\,+3KCl+3{{H}_{2}}O\]
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