RAJASTHAN PMT Rajasthan - PMT Solved Paper-2002

  • question_answer
    When aliphatic aldehyde heat with Fehling solution product formed is:

    A)  \[CuO\]                              

    B)  \[C{{u}_{2}}O\]               

    C)  \[CuS{{O}_{4}}\]             

    D)  \[Cu\]

    Correct Answer: B

    Solution :

    Aliphatic aldehyde on heating with Fehling solution produces red precipitate of \[C{{u}_{2}}O\]. \[R-CHO+2Cu{{(OH)}_{2}}+NaOH\xrightarrow{{}}\]                 \[RCO{{O}^{-}}+N{{a}^{+}}+\underset{\operatorname{Re}d\,ppt.}{\mathop{C{{u}_{2}}O}}\,+3{{H}_{2}}O\]


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