RAJASTHAN PMT Rajasthan - PMT Solved Paper-2007

  • question_answer
    Phenol and benzoic acid may be distinguished by

    A) \[NaHC{{O}_{3}}\]                          

    B)        \[NaOH\]

    C)        \[Na\]                                  

    D)        \[PC{{l}_{3}}\]

    Correct Answer: A

    Solution :

    Phenol and benzoic acid can be distinguished by \[NaHC{{O}_{3}}\] because being stronger acid only benzoic acid reacts with it and phenol does not react. Effervescences of \[C{{O}_{2}}\] confirms presence of \[COOH\] group. Phenol and benzoic acid react with other reagents \[(NaOH,\,\,Na,\,\,PC{{l}_{5}})\] given as choices. So, they cannot be used to distinguish them.


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