RAJASTHAN PMT Rajasthan - PMT Solved Paper-2008

  • question_answer
    \[H-O-H\] bond angle in \[{{H}_{2}}O\] is \[{{104.5}^{o}}\] and not \[{{109.28}^{o}}\] because of

    A)  lone pair-lone pair repulsion

    B)         lone pair-bond pair repulsion

    C)         bond pair-bond pair repulsion

    D)         high electronegativity of oxygen

    Correct Answer: A

    Solution :

    The hybridisation of oxygen in water molecule is\[s{{p}^{3}}\]. So, water molecule must be tetrahedral and have bond angle\[{{109}^{o}}28\]. But due to the presence of two lone pair of electrons on oxygen atom (repulsion between lone pair-lone pair) the bond angle decreases about \[{{104.5}^{o}}\] and the geometry becomes distorted tertrahedral or \[V-\]shaped.


You need to login to perform this action.
You will be redirected in 3 sec spinner