Uttarakhand PMT Uttarakhand PMT Solved Paper-2008

  • question_answer
    The ratio of amounts of\[{{H}_{2}}S\]needed to precipitate all the metal ions from 100 mL of 1 M\[AgN{{O}_{3}}\]and 100 mL of 1M\[CuS{{O}_{4}}\]will be

    A)  \[1:1\]          

    B)  \[1:2\]

    C)  \[2:1\]          

    D)  None of these

    Correct Answer: B

    Solution :

     100 mL of \[1\text{ }M\text{ }AgN{{O}_{3}}=0.1\text{ }mol\text{ }AgN{{O}_{3}}\] 100 mL of\[1M\text{ }CuS{{O}_{4}}=0.1\text{ }mol\text{ }CuS{{O}_{4}}\] \[\underset{\begin{smallmatrix}  2\,mol \\  0.1\,mol \end{smallmatrix}}{\mathop{2AgN{{O}_{3}}}}\,+\underset{\begin{smallmatrix}  1\,mol \\  0.05\,mol \end{smallmatrix}}{\mathop{{{H}_{2}}S}}\,\xrightarrow[{}]{{}}A{{g}_{2}}S+2HN{{O}_{3}}\] \[\underset{\begin{smallmatrix}  1\,mol \\  0.1\,mol \end{smallmatrix}}{\mathop{CuS{{O}_{4}}}}\,+\underset{\begin{smallmatrix}  1\,mol \\  0.1\,mol \end{smallmatrix}}{\mathop{{{H}_{2}}S}}\,\xrightarrow[{}]{{}}CuS+{{H}_{2}}S{{O}_{4}}\] \[\therefore \] Ratio of the amounts of H^S obtained \[=0.05:0.1=1:2\]


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