Uttarakhand PMT Uttarakhand PMT Solved Paper-2009

  • question_answer
    The compound, with which ethanal does not react, is

    A)  \[HCl\]          

    B)  \[C{{l}_{2}}\]

    C)  \[PC{{l}_{5}}\]          

    D)  aq \[NaHS{{O}_{3}}\]

    Correct Answer: A

    Solution :

     \[HCl\]is a strong inorganic acid, hence it does not react with ethanal whereas with other given reagents, it reacts in the following manner: \[\underset{ethanal}{\mathop{C{{H}_{3}}CHO}}\,+C{{l}_{2}}\xrightarrow[{}]{{}}\underset{chloral}{\mathop{CC{{l}_{3}}CHO}}\,\] \[C{{H}_{3}}CHO+PC{{l}_{5}}\xrightarrow[{}]{{}}C{{H}_{3}}CHC{{l}_{2}}\] \[C{{H}_{3}}CHO+HCl\xrightarrow[{}]{{}}No\text{ }reaction.\]


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