Uttarakhand PMT Uttarakhand PMT Solved Paper-2010

  • question_answer
    \[[CoBr{{(N{{H}_{3}})}_{5}}]S{{O}_{4}}\]and\[[CoS{{O}_{4}}{{(N{{H}_{3}})}_{5}}]Br\]are related to each other as

    A)  ionisation isomers

    B)  linkage isomers

    C)  coordinatiom isomers

    D)  optical isomiers

    Correct Answer: A

    Solution :

     The compounds which have same molecular formulae but give different ions in solution are called ionisation isomers eg, \[[CoBr{{(N{{H}_{3}})}_{5}}]S{{O}_{4}}{{[CoBr{{(N{{H}_{3}})}_{5}}]}^{2+}}+SO_{4}^{2-}\] It gives test of\[SO_{4}^{2-}\]ions. \[[CoS{{O}_{4}}{{(N{{H}_{3}})}_{5}}]Br{{[CoS{{O}_{4}}{{(N{{H}_{3}})}_{5}}]}^{+}}+B{{r}^{-}}\] it gives test of\[B{{r}^{-}}\]ions.


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