VIT Engineering VIT Engineering Solved Paper-2008

  • question_answer
    A Wittig reaction with an aldehyde gives

    A)  ketone compound -

    B)  a long chain fatty acid

    C)  olefin compound

    D)  epoxide

    Correct Answer: C

    Solution :

     This is also a mean of preparing alkene where the position of the double bond is definite. In Wittig reaction, aldehyde \[(-CHO)\] and ketone  react with methylene triphenyl phosphine \[[{{({{C}_{6}}{{H}_{5}})}_{3}}P=C{{H}_{2}}]\] to give alkene. \[C{{H}_{3}}CHO+{{({{C}_{6}}{{H}_{5}})}_{3}}P=C{{H}_{2}}\xrightarrow{{}}\]              \[\underset{\Pr opene}{\mathop{C{{H}_{3}}-CH}}\,=\underset{\begin{smallmatrix}  triphenyl\,\,phosphine \\  oxide \end{smallmatrix}}{\mathop{C{{H}_{2}}+{{({{C}_{6}}{{H}_{5}})}_{3}}P=O}}\,\]


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