The branch of physics which deals with the propagation, nature and behaviour of light is known as optics.
Light
Light is a form of energy -which enables human beings and creatures to 'see' things. When light emitted from an object or reflected from the object enters our eyes we are able to see the object. We can't see an object in dark even if we are in light because there is no light coming from the object to our eyes. Light is an electromagnetic radiation which exhibits properties like a wave as well as a particle. It always propagates in a straight line. Light travels with a speed nearly equal to\[3\times {{10}^{8}}m/s\]According to current theories, no material particle can travel at a speed greater than the speed of light.
Luminous and Non-luminous Objects
Luminous objects are those which emit its own light e.g., sun, glowworm, burning candle, electric lights. Non-luminous objects do not give out its own light but are visible only when light from a luminous object falls on it. e.g., moon, earth, table, paper, etc.
Transparent Translucent and Opaque materials
Transparent materials are those which allow most of light to pass through them. Example: Glass, water, air. Translucent materials allow only a part of light to pass through it. We cannot see distinctly through them. Example: greased paper, Paraffin wax, etc.
Opaque materials: do not allow any light to pass through it. They reflect or absorb all the light that falls on them. Example: Books, desk, stone, rubber, trees, etc.
Reflection of Light
Reflection of Light: When light hits an opaque material, the light may be absorbed by the material and converted into heat energy. If light is not absorbed, it is bounced back or reflected at the surface of material. The turning back of light in the same medium is called reflection of light.
Laws of reflection
The angle of incidence ‘i’ is equal to the angle of reflection ‘r’
At the point of incidence, the incident rays, the normal to the surface and the reflected ray all lie in the same plane.
Reflection by Plane Mirrors
Plane mirror is a looking glass which is highly polished on one surface and is silvered on the other surface. When a light ray strikes the polished surface, it is reflected by the silvered surface. An 'image' is defined as the impression of an object carried over and formed by light reflected from it.
Use of plane mirrors
(a) Plane mirrors are primarily used as looking glasses.
(b) Since, a combination of mirrors can produce multiple images, they are used to provide false dimensions in showrooms.
(c) They are also used as reflectors in solar cookers.
(d) Plane mirrors are used in the construction of a periscope.
Any motion that repeats itself in equal intervals of time is called periodic motion. Aperiodic motion can be represented in terms of sines and cosines, so it is called a harmonic motion. The uniformly rotating earth represents a periodic motion that repeats itself at every 24 hours.
Simple Harmonic Motion (S.H.M.)
Oscillatory motion in which the acceleration of the particle is directly proportional to the displacement and directs towards a fixed point in a direction opposite to displacement is called simple harmonic motion abbreviated as S.H.M. If a particle performs oscillatory motion such that its acceleration (a) and displacement (x) are related as below\[a\propto -x\], then the motion of particle is simple harmonic. An oscillatory motion is always periodic but a periodic motion may not be oscillatory.
Examples of S.H.M.
(i) clock pendulum,
(ii) oscillating liquid in a U-tube,
(iii) oscillating block in a liquid,
(iv) oscillating frictionless piston fitted in a cylinder filled with ideal gas, etc.
Sound
Sound is a form of energy which produces a sensation of hearing in our ears.
Source of Sound and its Propagation
A source of vibration (vibration means a kind of rapid to and fro motion of an object) is normally a source of sound. When we pluck a string of guitar or sitar or veena it produces sound. Similarly vibrations of wings of bee or mosquito. Sound is emitted by vibrating source and is transmitted through a material medium producing sensation of hearing in our ears. The motion of a vibrating source sets up waves in the surrounding medium.
Sound Needs a Material Medium for its Propagation
In the absence of medium (air) around the source, sound is not being propagated and light (electromagnetic) waves travel through the vacuum.
Mechanical Waves
A mechanical wave is a periodic disturbance which requires a material medium for its propagation. The properties of these waves depend on the medium so they are known as elastic waves, such as sound-waves, water waves, Waves in stretched string. On the basis of motion of particles the mechanical waves are classified into two parts.
Transverse wave: When the particles of the medium vibrate in a direction perpendicular to the direction of propagation of the wave, the wave is known as the transverse wave. For example, waves produced in a stretched string, waves on the surface. These waves travel inform of crests and troughs. These waves can travel in solids and liquids only.
Longitudinal wave: When the particles of the medium vibrate along the direction of propagation of the wave then the wave is known as the longitudinal wave. For example sound wave in air, waves in a solid rod produced by scrabbing etc. These waves travel in the form of compressions and rarefactions. These waves can travel in solids, liquids more...
Temperature is defined as the degree of hotness or coldness of a body. It is a scalar quantity Its S.I. unit is kelvin (K). Heat is a form of energy -which causes sensation of hotness or coldness. The flow of heat is always from higher temperature to lower temperature. No heat flows from one body to other, when both the bodies are at the same temperature. The two bodies are said to be in thermal equilibrium. The SI unit of heat is joule. Its CGS unit is calorie, 1 cal = 4.2 joule
Measurement of Temperature
A branch of science which deals with the measurement of temperature of a substance is called thermometry. Thermometer is a device used to measure the temperature. Thermometer used for measuring very high temperatures are called pyrometer.
Relationship between Different Scales of Temperature
\[\frac{C-0}{100}=\frac{F-32}{212-32}=\frac{K-273.16}{373.16-273.16}\]=\[\frac{R-0}{80-0}=\frac{Ra-460}{672-460}\]\[{{T}^{0}}(K)=({{t}^{0}}C+273.16)\] Normal temperature of human body is 310.15 K\[({{37}^{0}}C={{98.6}^{0}}F)\] STP or NTP implies 273.15 K \[({{0}^{0}}C={{32}^{0}}F)\]
Ideal-gas Equation and Absolute Temperature
The equation, PV= nRT where, n = number of moles in the sample of gas R = universal gas constant; (its value is 8.31\[J\,mo{{l}^{-1}}{{K}^{-1}}\]), is known as ideal-gas equation. It is the combination of following three laws
(i) Boyle's law: When temperature is held constant, the pressure is inversely proportional to volume. i.e., \[P\propto \frac{1}{V}\](at constant temperature)
(ii) Charters law: When the pressure is held constant, the volume of the gas is directly porportional to the absolute temperature. i.e., \[V\propto T\](at constant pressure)
(iii) Avogadro's law: When the pressure and temperature are kept constant, the volume is directly proportional to the number of moles of the ideal gas in the container. i.e., \[V\propto n\](at constant pressure and temperature)
Absolute Temperature
The lowest temperature of\[-\,273.16{}^\circ C\] at which a gas is supposed to have zero volume and zero pressure and at which entire molecular motion stops is called absolute zero temperature. A new scale of temperature starting with \[-273.16{}^\circ C\]by Lord Kelvin as zero. This is called Kelvin scale or absolute scale of temperature. \[T\left( K \right)=t{}^\circ C+273.16\]
Thermal Expansion
The increase in the dimensions of a body due to the increase in its temperature is called thermal expansion.
Linear expansion: The fractional increase in length per \[{}^\circ C\] rise in temperature is called coefficient of linear expansion. Coefficient of linear expansion, \[\alpha =\frac{\left( \frac{\Delta \ell }{\ell } \right)}{\Delta T}=\frac{d\ell }{\ell dT}\]
Superficial expansion: On increasing the temperature of a solid, its area increases. This increase in area is referred as superficial expansion. Coefficient a/superficial expansion is defined as the fractional increase in area per \[{}^\circ C\]rise in temperature. i.e., Coefficient of a real expansion \[\beta =\frac{\Delta A/A}{\Delta T}=\frac{dA}{AdT}\]
Cubical expansion: On increasing the temperature of a solid, its volume increases. This increase in volume with increase in temperature is called cubical more...
Those quantities which can describe the laws of physics and possible to measure are called physical quantities. The physical quantities which do not depend upon other physical quantities are called fundamental quantities. In Standard International (S.I.) system the fundamental quantities are mass, length, time, temperature, luminous intensity, electric current and amount of substance. The physical quantities which depend on fundamental quantities are called derived quantities e.g. speed, acceleration, force, etc.
Units
The unit of a physical quantity is the reference standard used to measure it.
Types of Units
Fundamental Units
The units defined for the fundamental quantities are called fundamental or base units.
Fundamental Physical quantity
Mass (M)
Length (L)
Time (T)
Temperature
(\[\theta \]or k)
Electric current (I)
Luminous intensity
Amount of Substance
Fundamental unit
Kilogram (kg)
Meter (m)
Second (s)
Kelvin (k)
Ampere (A)
Candela (cd)
Mole (mol)
Derived Units
The units defined for the derived quantities are called derived units, e.g. unit of speed or velocity (metre per second),
Acceleration (metre per second\[\sec on{{d}^{2}}\]) etc.
Dimensions
The limit of a derived quantity in terms of necessary basic units is called dimensional formula and the raised powers on the basic units are dimensions.
Elasticity and Plasticity
The property of the body to regain its original configuration (length, or shape) when the deforming forces are removed is called elasticity. On the other hand, if the body does not have any tendency to regain its original configuration on removal of deforming force the body is called plastic body and this property is called plasticity.
Perfectly elastic body: A body which regains its original configuration immediately and completely after the removal of deforming force from it, is called perfectly elastic body. Quartz and phosphor bronze, are closed to perfectly plastic body.
Perfectly plastic body: A body which does not regain its original configuration at all on the removal of deforming force, however small the deforming force may be is called perfectly plastic body. Putty mid mud are closed to perfectly plastic body.
Stress
The internal restoring force acting per unit area of a body is called stress. i.e., Stress = Restoring force/Area
Strain
The ratio of change in configuration to the original configuration is called strain.
\[strain=\frac{Change\,in\,\,configuration}{Original\,Configuration}\]
Strain being the ratio of two like quantities has no units and dimensions.
Elastic Limit
Elastic limit is the upper limit of deforming force up to which, if deforming force is removed, the body regains its original form completely and beyond which, if deforming force is increased, the body loses its property of elasticity and gets permanently deformed.
Hooke's low
It states that within the elastic limit stress is directly proportional to strain.
i.e.. Stress \[\propto \]strain or Stress =\[E\times \] strain
Stress or \[\frac{Stress}{strain}=E=Cons\tan t\]
Here E is the coefficient of proportionality and is called modulus of elasticity or coefficient of elasticity of a body:
Materials-Ductile, Brittle and Elastomers
(i) Ductile materials: The materials which have large range of plastic extension are called ductile materials. They can be drawn into thin wires, e.g., copper, silver, aluminium, iron, etc.
(ii) Brittle materials: The materials which have very small range of plastic extension are called brittle materials. These materials break as soon as the stress is increased beyond the elastic limit, e.g., glass, ceramics, cast iron, etc.
(iii) Elastomers: The materials which can be stretched to large values of strain are called elastomers. e.g., rubber, elastic tissue of aorta, etc.
Young's modulus of elasticity (Y): It is defined as the ratio of normal stress to the longitudinal strain within the elastic limit. Thus, \[Y=\frac{Normal\,Stress}{Longitudinal\,Strain}\] or, \[Y=\frac{F/\pi {{r}^{2}}}{\Delta l/{{L}_{0}}}=\frac{Mg{{L}_{0}}}{\pi {{r}^{2}}\Delta l}\]
Thermal Stress
When a rod is rigidly fixed at its two ends and its temperature is changed, then a thermal stress is set up in the rod. And the corresponding strain developed is called thermal strain, Thermal stress \[=\frac{Force}{Area\,\,of\,\,cross\,\,\sec tion}=\frac{F}{A}=Y\alpha \Delta \theta \] Area of cross section A where \[\alpha \] = coefficient of linear expansion of the rod \[\Delta \theta \] = change in temperature. more...
The pollutants may be inorganic, biological or radiological in nature.
(i) Bio-degradable pollutants are domestic wastes which are rapidly decomposed by micro-organisms.
(ii) Non-biodegradable pollutants include chemicals, mercuric salts, lead compounds, pesticides, etc.
(iii) Natural pollution is caused by radioactive substances, volcanic eruptions, forests and mines fires floods, etc.
(iv) Artificial pollution is caused by industries, thermal plants, automobile, exhausts, sewage, etc.
Environment
Environment: The conditions existing around animal or human life.
Atmosphere: The gaseous envelop surrounding the earth. It has been classified into following regions:-
(i) Stratosphere: The layer of the earth's atmosphere above the troposphere and below the mesosphere.
(ii) Troposphere: The lowest region of the atmosphere extending from earth's surface to the lower boundary of the stratosphere. In this region, human beings along with other organisms live. It contains water vapour and is greatly affected by air pollution.
Note: The other two layers are Thermosphere and Mesosphere.
Air pollution
Air pollution: The major air pollutants are
(i) Carbon monoxide (CO): It is produced by incomplete combustion of gasoline in motor vehicles, wood, coal, inceneration and forest fires. It is treacherous and deadly poisonous gas. It induces headache, visual difficulty coma and death. It blocks the normal transport of oxygen from the lungs to other parts of the body.
(ii) Sulphur dioxide\[(S{{O}_{2}})\]: It is produced by petrol combustion, coal combustion, and petrol refining and smelting operations. It hinders the movement of air in and out of lungs. It is particularly poisonous to trees causing chlorosis and dwarfing. In presence of air it is oxidised to \[S{{O}_{3}}\] which is also irritant.
\[2S{{O}_{2}}+{{O}_{2}}(air)\to 2S{{O}_{3}}\]
In presence of moisture \[S{{O}_{3}}\] is converted into highly corrosive sulphuric acid.
\[S{{O}_{3}}+{{H}_{2}}O(moisture)\to {{H}_{2}}S{{O}_{4}}\]
It attacks marble, limestone, vegetation, paper and textiles and injurious to human beings.
(iii) Oxides of nitrogen: \[N{{O}_{2}}\] and NO, Source - combustion of coal, gasoline, natural gas, petroleum refining, chemical plants, manufacturing explosives and fertilizers, tobacco smoke. Breathing \[N{{O}_{2}}\] causes chlorosis to plants and chronic lung conditions leading to death. \[N{{O}_{2}}\] reacts with moisture to form acids.
\[2N{{O}_{2}}+{{H}_{2}}O\to HN{{O}_{2}}+HN{{O}_{3}}\],
\[3HN{{O}_{2}}\to 2NO+HN{{O}_{3}}+{{H}_{2}}O\]
(iv) Smoke, dust:
Sources: cement works, iron and steel works, gas works, power generating stations.
Smog: It is a mixture of smoke and fog in suspended droplet form. It is of two types:
London smog or classical smog: It is coal smoke plus fog. The fog part is mainly \[S{{O}_{2}}\] and \[S{{O}_{3}}\].It has sulphuric acid aerosol. It causes bronchial irritation and acid rain. It is reducing in nature.
Photochemical smog or Los Angeles smog: The oxidised hydrocarbons and ozone in presence of humidity cause photochemical smog. Hydrocarbons \[+{{O}_{2}}\], \[N{{O}_{2}}\] NO, O, \[{{O}_{3}}\] \[\to \] Peroxides, formaldehyde, peroxyacetylnitrate (PAN), acrolein etc. It is oxidising in nature and causes irritation to eyes, lungs, nose, and asthamatic attack and damage plants.
Acid rain: The oxides of C, N and S present in the atmosphere, more...
Chemistry is a branch of science which deals with study of matter and various changes it undergoes. It deals with the preparation, properties, reactions and structures of chemical elements and compounds. For convenience the study of chemistry is sub-divided into various branches such as:
(i) Inorganic chemistry (ii) Organic chemistry (iii) Physical chemistry
(iv) Analytical chemistry (v) Industrial chemistry
Valency
During the formation of molecules of compounds, atoms combine in certain fixed proportions. This is because of the fact that different atoms have different combining capacities. The combining capacity of an atom or radical is known as its valency.
Ions or radicals
In addition to atoms and molecules, a third type of particles occurs in substances. These particles, called ions, or atoms or group of atoms that carry an electrical charge. An ion is formed when electrons are removed from or added to an atoms or group of atoms. When electrons is/are removed the resulting ion is called a cation or basic radical. A cation is positively charged ion. (e.g\[N{{a}^{+}}\]. When electron is/are added the resulting ion is called an anion or acidic radicals. An anion is negatively charged ion e.g.,\[(C{{l}^{-}},O_{2}^{2-})\]An ion or radical is classified as monovalent, divalent, trivalent or tetravalent when the number of charges over it is 1,2,3 or 4 respectively.
Formula of Elements and Compounds
Formula of dements: The molecule of an element is denoted by writing the symbol of the element and, to the right and below it, a number expressing the number of atoms in the molecule.
Formula of compound: A molecule of a compound maybe made up of atom of different elements linked up together chemically and in definite proportion by weight.
Chemical formula: It is of two types:
(i) Molecular formulae: Chemical formulae that indicate the actual number and type of atoms in a molecule is called molecular formulae.
(ii) Empirical formulae: Chemical formulae that indicate only the relative number of atoms of each type in a molecule is called empirical formulae.
Equivalent weight
(i) Equivalent weight of element \[=\frac{Atomic\,\,weight\,\,of\,\,element}{Valency\,\,of\,\,element}\]
(ii) Eq. wt of an acid/base\[=\frac{Molecular\,\,mass}{Basicity\,\,of\,\,acid/Acidity\,\,of\,\,base}\]
(iii) Eq. wt of salts\[=\frac{Formula\,\,mass}{(Valency\,\,of\,\,cation)(No.of\,\,cations)}\]
Expression of strength /concentration of Solution
(i) Mass percent = \[\frac{Weight\,\,of\,\,solute(gm)}{Weight\,\,of\,\,solution(gm)}\times 100\]
(ii) Normality \[=\frac{numer\,\,of\,\,gram\,\,equivalents\,\,of\,solute}{Volume\,\,of\,solution\,(lit.)}\]
(iii) Molarity =\[\frac{Number\,\,of\,\,gram\,\,moles\,\,of\,\,solute}{Volume\,\,of\,\,solution(lit.)}\]
(iv) Molality \[=\frac{Gram\,\,moes\,\,of\,\,solute}{weight\,\,of\,\,solent\,(kg)}\]
(v) Mole fraction: Mole fraction of solute \[={{X}_{A}}=\frac{{{n}_{A}}}{{{n}_{A}}+{{n}_{B}}}\]
Mole fraction of solvent \[={{X}_{B}}=\frac{{{n}_{B}}}{{{n}_{A}}+{{n}_{B}}}\]
\[{{X}_{A}}+{{X}_{B}}=1\]
Chemical reaction: The process in which a substance undergoes change to produce new substances with new properties are known as chemical reaction. For example magnesium carbonate when heated produces magnesium oxide and carbon dioxide (i.e. new substances with new properties). A chemical change is generally accompanied by a change of state, change of colour, evolution of a gas or change of temperature etc.
Chemical equation: The qualitative representation of a chemical reaction in a short hand or concise form in term of symbols and formulae, is called a chemical equation.
Introduction
Chemistry has helped significantly in meeting human needs by providing chemical fertilizers, improved varieties of insecticides and pesticides to increase the yield of crops and fruits. It has given us a large number of lifesaving drugs. Also chemical industries manufacturing polymers, soaps, detergents, glass, ceramics etc.
Industrially Important Compounds Glass
It consists of a mixture of two or more silicates.
Preparation of glass:
Common glass (or soft glass): It is used to make bottles, glass wares etc. and is obtained by heating together silica (in the form of sand), sodium carbonate or sodium sulphate and chalk or lime stone (calcium carbonate). Some broken glass and a little coke are usually added. The glass so prepared consists of silicates of sodium and calcium.
Hard glass: For preparation of hard glass \[{{K}_{2}}C{{O}_{3}}\] is used in place of\[N{{a}_{2}}C{{O}_{3}}\]. It consists of a mixture of calcium and potassium silicates.
Physical properties of glass: Hard, rigid, high viscosity, bad conductor of heat and electricity, brittle, etc.
Blowing: It is a method to cast the molten glass into different moulds. There are two different methods of glass blowing (i) Free blowing and (ii) Mould blowing
Free blowing: It involves the blowing of air to inflate the molten glass which is gathered at one end of the blow pipe to give the desired shape.
Mould blowing: This method was developed after' the technique of free blowing. In this method, molten glass is inflated into a wooden or metal carved mould with the help of blow pipe which gives the molten glass the shape and design of the interior of the mould.
Chemical properties of glass
(i) It is resistant to action of air and acids except hydroflouric acid.
(ii) It is alkaline in nature.
(iii) It slowly reacts with water to form alkaline solution.
Types of Glass
(i) Silica glass: For this type of glass the raw material used is 100% pure form of quartz. It is quite expensive. It is used in the manufacture of laboratory apparatus. It has low thermal expansion. Its softening point is very high and it is resistant to a wide variety of chemicals.
(ii) Alkali silicate glass: For it the raw materials used are sand and soda. It is also called water glass because it is soluble in water and used only as a solution. It is generally used to make gums and adhesives.
(iii) Lead glass: For this type of glass lead oxide is added to ordinary glass. The addition of lead oxide increases the density and also the refractive index. This type of glass is used for the manufacture of ornamental glass ware, decorative articles etc.
(iv) Optical glass: This type of glass is used in the manufacture of optical instruments like binoculars, spectacles, lenses, prisons, telescopes, microscopes etc. It is transparent and can be grounded into the required more...
Wohler prepared the first organic compound urea while preparing ammonium cyanate.
Classification of organic compounds:
The existence of two or more chemical compounds with the same molecular formula but having different properties owing to different arrangement of atoms within the molecule is termed as isomerism
Hydrocarbons: All those compounds which contain just carbon and hydrogen are called hydrocarbons.
Functional group: The atom or group of atoms which determine the properties of a compound is known as functional group. e.g. \[-OH\] (alcohol), -CHO (aldehyde), > C = C < (alkene), \[-C\equiv C-\] (alkyne), etc.
Homologous Series: A series of compounds in which the same functional group substitute’s hydrogen in a carbon chain is called a homologous series, e.g. \[C{{H}_{3}}Cl\] .and \[{{C}_{2}}{{H}_{5}}Cl\] differ by a \[-C{{H}_{2}}\] unit.
Nomenclature: Chemists developed a set of rules, for naming organic compounds based on their structures which is known as IUPAC rules. The IUPAC name of an organic compounds consists of three parts.
Prefix - word root - Suffix
Word root: A word root indicates the nature of basic carbon skeleton.
In case a functional group is present, it is indicated in the name of the compound with either as a prefix or as suffix.
While adding the suffix to the word root the terminal 'e' of carbon chain is removed
If the carbon chain is unsaturated then the final 'ane' in the name of the carbon chain is substituted by 'ene' or ‘yne’ respectively for double and triple bonds.
Biodiversity refers number and types of wide variety of plants and animals present on earth.
In 1773, Swedish botanist Carolus Linnaeus formulated the system of Binomial Nomenclature in his book 'Species plantarum''. In binomial system, each name is expressed in two parts i.e., generic name and specific name.
Taxon is the branch of biology that deals with the framing of laws and principles for classifying the organisms on the basis of their characteristics and evolutionary relationships.
The hierarchial system of classification was introduced by
Species is defined as "the smallest real basic unit of taxonomy which is reproductively isolated from other group of individuals".
Genus is a group of closely related species that are alike in broad features of their organization.
Family is a group of related genera having several common characters.
Generally, Order and other higher taxonomic categories are identified based on the aggregates of characters.
A Class is made of one or more related orders.
The term Phylum is used for animals while Division is commonly employed for plants.
Kingdom is the highest taxonomic category. All plants are included in Kingdom Plantae. All animals are included in Kingdom Animalia.
Herbarium is a collection of pressed and dried plant specimens that are preserved on paper sheets.
In Botanical garden, various plants groups are grown for scientific study, conservation, public education, aesthetics, and recreation. The famous botanical gardens are at Kew (England), Indian Botanical Garden, Howrah (India) and
National Botanical Research Institute, Lucknow (India).
Museum is a building used for the preservation, storage and exhibition of inanimate objects.
Zoological park or zoological garden or zoo is a place where wild animals are kept in protected environment under human care. These animals are kept for public exhibition.
History of Classification
Biological classification was first proposed by Aristotle who used simple morphological characters to classify plants and animals.
Linnaeus initially separated plants and animals in two Kingdoms i.e., Kingdom Plantae and Kingdom Animalia.
Most accepted System of classification is five system classification which was given by Whittaker.